Journal of the American Chemical Society p. 6372 - 6375 (1984)
Update date:2022-08-02
Topics:
Ladika, Mladen
Stang, Peter J.
Schiavelli, Melvyn D.
Kowalski, Mark H.
The solvolytic behaviot of ethenoanthracenyl (3a) and etheno-9,10-dimethylanthracenyl (3b) triflates was examined.Despite the strain inherent in these systems, 3a reacts 105 times faster than cyclohexenyl triflate and 11 times faster than the unstrained cis-2-butenyl triflate.These results are explained by an unusual aryl stabilization of the incipient vinyl cations.
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