Absolute Configurations, Maximum Rotations, and Kinetics of Thermal Racemization of the 1-Phenyl-2-deuteriocyclopropanes

DOI: 10.1021/ja00333a042

Source and publish data:

Journal of the American Chemical Society p. 6364 - 6367 (1984)

Update date:2022-08-05

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Authors:

Baldwin, John E.

Barden, Timothy C.

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Article abstract of DOI:10.1021/ja00333a042

From precursors of known absolute configurations and optical purities have been prepared (1S,2R)-(-)-cis-1-phenyl-2-deuteriocyclopropane and the (1R,2R)-(+)-trans isomer.The predicted kinetics of racemization for the (-)-cis isomer at 309.3 deg C based on

Full text of DOI:10.1021/ja00333a042

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