Catalysis by lithium perchlorate in dichloromethane: Diels-Alder reactions and 1,3-Claisen rearrangements

DOI: 10.1016/S0040-4020(01)87187-8

Source and publish data:

Tetrahedron p. 6025 - 6030 (1993)

Update date:2022-08-04

Topics:

Authors:

Reetz Reetz

Gansauer

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Article abstract of DOI:10.1016/S0040-4020(01)87187-8

Lithium perchlorate suspended in dichloromethane is an efficient catalyst (4-25 mol-%) for stereoselective Diels-Alder, hetero-Diels-Alder and regioselective 1,3-Claisen rearrangements; this process is milder, safer and environmentally less precarious tha

Full text of DOI:10.1016/S0040-4020(01)87187-8

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