Tetrahedron p. 2183 - 2187 (1984)
Update date:2022-08-05
Topics:
Adinolfi, Matteo
Barone, Gaspare
Lanzetta, Rosa
Laonigro, Guglielmo
Mangoni, Lorenzo
Parrilli, Michelangelo
The addition of ICl and IBr to 1-methyl-4-t-butylcyclohexene has been investigated in chloroform and carbon tetrachloride and the distribution of the produced trans-iodohalogenides has been determined by NMR spectroscopy.The stereoselectivity of the addition was found to be determined by both the reversible electrophilic first step and the nucleophilic second step.The higher stereoselectivity of the addition of IBr is interpreted on the basis of the higher softness of bromide ion with respect to chloride ion.
View MoreWuxi Pharma-Trading Import & Export Co.,Ltd.
Contact:+86-510-82304590 82716390
Address:Room 523,Youzu Alliance Building,No.88 Renmin Zhonglu,Wuxi,Jiangsu,China
Nanjing Qirui Material Co., Ltd.
Contact:+86-25-52320053
Address:F4-5, #17 Building, Chuang Yi Yuan, No.6 Guanghua East Street, Nanjing, 210007 P.R.China
Chongqing KonAo Health Co.,Ltd
Contact:13687578375
Address:wuhan hubei china
Zhejiang Sanmei Chemical Industry Co., Ltd
Contact:86-579-87633213
Address:Huchu Industrial Zone, Qingnian Rd., Wuyi County, Zhejiang Prov., China.
Changzhou Sunsheng Chem Co., Ltd
Contact:+1-(989)-854-0648
Address:No. 28 Yinshan Rd., Xixiashu Industrial Park
Doi:10.1016/S0040-4039(02)01752-5
(2002)Doi:10.1248/cpb.15.350
(1967)Doi:10.1039/c39930000456
(1993)Doi:10.1021/jm00075a013
(1993)Doi:10.1016/0040-4020(95)00492-Q
(1995)Doi:10.1016/j.tet.2013.06.013
(2013)
