THERMOLYTIC RING OPENING OF ACYLOXYBENZOCYCLOBUTENES: AN EFFICIENT ROUTE TO 3-SUBSTITUTED ISOQUINOLINES

DOI: 10.1016/S0040-4039(00)98697-0

Source and publish data:

Tetrahedron Letters p. 3959 - 3962 (1985)

Update date:2022-08-04

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Authors:

Schiess, Peter

Huys-Francotte, Martine

Vogel, Caspar

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Article abstract of DOI:10.1016/S0040-4039(00)98697-0

Upon flash vacuum pyrolysis acyloxybenzocyclobutenes 4 rearrange through an intramolecular 1,5-acyl shift to 2-formylbenzyl ketones 6 which can be converted to 3-substituted isoquinolines 7.

Full text of DOI:10.1016/S0040-4039(00)98697-0

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