Tetrahedron p. 4355 - 4360 (1991)
Update date:2022-08-04
Topics:
Bessiere, Yvonne
Bessard, Yves
Kotani, Takayuki
Schlosser, Manfred
Three new model substrates of the chlorofluorocyclopropane type (6, 11 and 14) were submitted to silver ion-assisted ring opening.No rearrangement, but only fragmentation or direct solvolysis was found to take place.In the latter case, primary rather than tertiary 2-fluoroallyl alcohols are formed almost exclusively.Nucleophilic attack at the unsubstituted terminus of the 2-fluoroallyl cation is apparently favored for steric reasons.
View MoreNINGXIA DARONG CHEMICALS & METALLURGY CO.,LTD.
Contact:86-952-2179751
Address:Darong Road, Dawukou, Shizuishan, Ningxia 753001, China
Daqing New Century Fine Chemical Co., Ltd.(expird)
Contact:010-57126694
Address:No.39, jinxing cun, honggang district
Jiangsu Dacheng Pharmaceutical and Chemical Co.,Ltd
Contact:+86-0517-87036900
Address:Chuzhou Chemical park, Huai'an, Jiangsu Province
website:http://www.alwaychem.com
Contact:+86-532-8586-4000, 8586-5000
Address:NO.51, TAIPING ROAD, QINGDAO, CHINA. 266001
Contact:
Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District
Doi:10.1021/ja0661010
(2006)Doi:10.1016/j.tet.2018.09.044
(2018)Doi:10.1002/ejoc.200600744
(2006)Doi:10.1039/jr9630005807
(1963)Doi:10.1021/om060838g
(2007)Doi:10.1021/ja0654579
(2006)
