Tetrahedron p. 4355 - 4360 (1991)
Update date:2022-08-04
Topics:
Bessiere, Yvonne
Bessard, Yves
Kotani, Takayuki
Schlosser, Manfred
Three new model substrates of the chlorofluorocyclopropane type (6, 11 and 14) were submitted to silver ion-assisted ring opening.No rearrangement, but only fragmentation or direct solvolysis was found to take place.In the latter case, primary rather than tertiary 2-fluoroallyl alcohols are formed almost exclusively.Nucleophilic attack at the unsubstituted terminus of the 2-fluoroallyl cation is apparently favored for steric reasons.
View Moreshijiazhuang baisheng chem co.; ltd
Contact:86-0311-80790826
Address:shijiazhuang hebei
Jiangsu Willing Bio-Tech Co ltd
website:http://www.willingbio.com/
Contact:+86 18796908173
Address:No 18 Guoqiao Road
Tianjin Bright Future Technology Co., Ltd
Contact:0086-22-58016666
Address:NO.136 DongTeng Lake Street Tianjin Economic and Technology Development Area,Tainjin,China
Chengdu Biopurify Phytochemicals Ltd.
website:http://www.phytopurify.com
Contact:+86-28-82633397
Address:2F,No.11 Building,No.388 Rongtaidadao CNSTP,Wenjiang Zone,Chengdu,Sichuan, China
Chengdu Yunyi International Trade Co., Ltd
Contact:
Address:china
Doi:10.1021/ja0661010
(2006)Doi:10.1016/j.tet.2018.09.044
(2018)Doi:10.1002/ejoc.200600744
(2006)Doi:10.1039/jr9630005807
(1963)Doi:10.1021/om060838g
(2007)Doi:10.1021/ja0654579
(2006)
