Tetrahedron p. 4355 - 4360 (1991)
Update date:2022-08-04
Topics:
Bessiere, Yvonne
Bessard, Yves
Kotani, Takayuki
Schlosser, Manfred
Three new model substrates of the chlorofluorocyclopropane type (6, 11 and 14) were submitted to silver ion-assisted ring opening.No rearrangement, but only fragmentation or direct solvolysis was found to take place.In the latter case, primary rather than tertiary 2-fluoroallyl alcohols are formed almost exclusively.Nucleophilic attack at the unsubstituted terminus of the 2-fluoroallyl cation is apparently favored for steric reasons.
View MoreContact:(1) 206-3550089
Address:5115 NE 8TH PL, Renton, WA 98059 USA
Shanghai Haoyuan Chemexpress Co., Ltd.
website:https://www.chemexpress.com/
Contact:86-21-58950125
Address:No.3 Building, No.1999, Zhangheng Road, ZhangjiangHighTech Park, Shanghai, P.R.China,201203
Shandong Loyal Chemical industrial Co.,Ltd
Contact:0533-7451788
Address:Linzi Chemical Industrial Park, Zibo, Shandong Province
Jiangsu Feymer Technology Co., Ltd.
Contact:+86-512-58110132
Address:Fenghuang Town, Zhangjiagang City, Jiangsu Province, China
SHANDONG CREDAGRI CHEMICAL CO., LTD.
Contact:+86-531-88872050
Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.
Doi:10.1021/ja0661010
(2006)Doi:10.1016/j.tet.2018.09.044
(2018)Doi:10.1002/ejoc.200600744
(2006)Doi:10.1039/jr9630005807
(1963)Doi:10.1021/om060838g
(2007)Doi:10.1021/ja0654579
(2006)
