Stereochemistry in the Reaction of Optically Active Allylsilanes with m-Chloroperoxybenzoic Acid

DOI: 10.1021/jo00196a023

Source and publish data:

Journal of Organic Chemistry p. 4224 - 4226 (1984)

Update date:2022-07-29

Topics:

Authors:

Hayashi, Tamio

Okamoto, Yasuo

Kabeta, Keiji

Hagihara, Toshiya

Kumada, Makoto

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Article abstract of DOI:10.1021/jo00196a023

An optically active allylsilane (R)-(E)-1-phenyl-1-(trimethylsilyl)-2-butene (1) (81percent ee) was allowed to react with m-chloroperoxybenzoic acid (MCPBA) in dichloromethane to give, after acidic methanolysis, (S)-(E)-4-phenyl-3-buten-2-ol (2) (71-73per

Full text of DOI:10.1021/jo00196a023

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