Stereochemistry in the Reaction of Optically Active Allylsilanes with m-Chloroperoxybenzoic Acid

DOI: 10.1021/jo00196a023

Source and publish data:

Journal of Organic Chemistry p. 4224 - 4226 (1984)

Update date:2022-07-29

Topics:

Authors:

Hayashi, Tamio

Okamoto, Yasuo

Kabeta, Keiji

Hagihara, Toshiya

Kumada, Makoto

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00196a023

An optically active allylsilane (R)-(E)-1-phenyl-1-(trimethylsilyl)-2-butene (1) (81percent ee) was allowed to react with m-chloroperoxybenzoic acid (MCPBA) in dichloromethane to give, after acidic methanolysis, (S)-(E)-4-phenyl-3-buten-2-ol (2) (71-73per

Full text of DOI:10.1021/jo00196a023

Products guided by the article

Product name:(Z)-1-Phenyl-3-<(trimethylsilyl)oxy>-1-butene

Cas No:92075-83-7

R&D Labs maybe for 92075-83-7

Shanghai AoBo Bio-Pharmaceutical Technology Co., Ltd.

Contact:+86-21-51320130-801, 816

Address:Room 601, No. 1011, Halei Road, Zhangjiang High-Tech Park, Pudong, Shanghai
Hebei DaPeng Pharm & Chem Co., Ltd.

Contact:86-317-7298678,0576-88861898 88861908

Address:West Songmen Village, East Songmen Town, Wuqiao, Cangzhou, Hebei ,China
jiangsu senxuan pharmaceutical and chemical co.,ltd

Contact:86-523-87982810

Address:hongqiao industrial zone,taixing,jiangsu china
Hangzhou Hysen Pharma co.,Ltd.

website:http://www.hysenpharma.cn/

Contact:0086-571-88298791

Address:#701,Gudun Road Hangzhou
CHANGYI CITY FENGRUN FINE CHEMICAL CO.,LTD

website:http://www.fengrunhuagong.com

Contact:+86-536-7869976

Address:Changyi Coastal Economic Development Zone

Relevant to this article

Doi:10.1021/ja00884a015
(1963)
A NOVEL STEREOCONTROLLED SYNTHESIS OF (Z,Z)-3,13-OCTADECDIEN-1-YL ACETATE, THE SEX PHEROMONE OF SYNANTHEDON SPECIES

Doi:10.1016/S0040-4039(01)81267-3
(1984)
Doi:10.1021/ja01527a045
(1959)
Synthesis and group electronegativity implications on the electrochemical and spectroscopic properties of diferrocenyl meso-substituted porphyrins

Doi:10.1021/om060373u
(2007)
Direct observation of the oxidative addition of the aryl carbon-oxygen bond to a ruthenium complex and consideration of the relative reactivity between aryl carbon-oxygen and aryl carbon-hydrogen bonds

Doi:10.1021/ja067612p
(2006)
N-substituted cis-4a-(3-hydroxyphenyl)-8a-methyloctahydroisoquinolines are opioid receptor pure antagonists

Doi:10.1021/jm058261c
(2005)

Article Doi