Edge Article
Chemical Science
further optimization is required to enhance performance, these
processes dene an alternative to classical carbonylative
hydroaminomethylation via hydroformylation-reductive ami-
nation, which is presently limited to reactions of non-
conjugated olens. More broadly, these studies contribute to
an ever-growing body of catalytic C–C bond formations that
merge the characteristics of carbonyl and imine addition with
transfer hydrogenation.27
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Acknowledgements
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T. Muller, J. Walter and J. Weber, (Hoechst AG) DE
The Robert A. Welch Foundation (F-0038), the NSF (CHE-
1265504) and the University of Texas Center for Green Chem-
istry and Catalysis are acknowledged for partial support of this
research. The Deutsche Forschungsgemeinscha (DFG) post-
doctoral fellowship program (FR 3555/1-1) is acknowledged for
partial support (J.F.).
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