Vicarious Nucleophilic Substitution of Hydrogen in Nitrophenols and Polynitroarenes. Examples of Nucleophilic Addition to Nitrocyclohexadienonenitronate Anions

DOI: 10.1021/jo00197a057

Source and publish data:

Journal of Organic Chemistry p. 4562 - 4563 (1984)

Update date:2022-07-29

Topics: Nucleophilic addition Vicarious nucleophilic substitution

Authors:

Makosza, Mieczyslaw

Ludwiczak, Sergiusz

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Article abstract of DOI:10.1021/jo00197a057

The vicarious nucleophilic substitution of hydrogen in dinitrophenols with chloromethyl phenyl sulfone carbanion 1 follows an orientation pattern due to quinoid resonance structures of the dinitrophenolate anions which behave as dinitrocyclohexadiene deri

Full text of DOI:10.1021/jo00197a057

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