Vicarious Nucleophilic Substitution of Hydrogen in Nitrophenols and Polynitroarenes. Examples of Nucleophilic Addition to Nitrocyclohexadienonenitronate Anions

DOI: 10.1021/jo00197a057

Source and publish data:

Journal of Organic Chemistry p. 4562 - 4563 (1984)

Update date:2022-07-29

Topics: Nucleophilic addition Vicarious nucleophilic substitution

Authors:

Makosza, Mieczyslaw

Ludwiczak, Sergiusz

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00197a057

The vicarious nucleophilic substitution of hydrogen in dinitrophenols with chloromethyl phenyl sulfone carbanion 1 follows an orientation pattern due to quinoid resonance structures of the dinitrophenolate anions which behave as dinitrocyclohexadiene deri

Full text of DOI:10.1021/jo00197a057

Products guided by the article

Product name:Benzene, 1-methoxy-2,4-dinitro-5-[(phenylsulfonyl)methyl]-

Cas No:92241-28-6

R&D Labs maybe for 92241-28-6

Chengdu Sino-Strong Pharmaceutical Co.,Ltd.

website:http://www.sino-strong.com.cn

Contact:+86-28-82666753

Address:459 West haike road,Cross-straits technological industry park, Wenjiang district,Chengdu, P.R.China
JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD

website:http://www.xypharm.com/

Contact:+86-515-84383317

Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China
Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou
SHIJIAZHUANG CHENSHI IMPORT AND EXPORT CO.,LTD

Contact:+86-311-89871056

Address:RM2017 BUILDING CTIANSHAN GALAXY PLAZA,NO168 CHANGJIANG ROAD,GAOXIN DISTRICT,SHIJIAZHUANG CITY, HEBEI,CHINA
Shanghai Sinofluoro Scientific Co., Ltd

Contact:+86-21-64279360

Address:Room 1006,Building 3,#58 East Xinjian Road, Shanghai ,201100,China,

Relevant to this article

Doi:10.1021/jo01066a082
(1961)
Potent CDC25B and PTP1B phosphatase inhibitors: 2′,4′,6′-trihydroxylchalcone derivatives

Doi:10.1007/s00044-014-1264-x
(2015)
Doi:10.1016/S0040-4020(01)99327-5
(1984)
N-Propylphthalimide-substituted bis-(NHC)PdX₂ complexes: synthesis, characterization and catalytic activity in direct arylation reactions

Doi:10.1007/s11243-017-0190-4
(2018)
Doi:10.1006/jmbi.2001.4706
(1932)
Novel heterogeneous catalyst systems based on Pd(0) nanoparticles onto amine functionalized silica-cellulose substrates [Pd(0)-EDA/SCs]: Synthesis, characterization and catalytic activity toward C-C and C-S coupling reactions in water under limiting basic conditions

Doi:10.1016/j.molcata.2015.07.005
(2015)

Article Doi