Existence and Reactivity of Bicyclic Annulenones. 4-Phenylbicycloocta-1(5),3,6-triene-2,8-dione

DOI: 10.1021/jo00198a009

Source and publish data:

Journal of Organic Chemistry p. 4616 - 4618 (1984)

Update date:2022-08-03

Topics:

Authors:

Gavina, Francisco

Costero, Ana M.

Luis, Santiago V.

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Article abstract of DOI:10.1021/jo00198a009

The elusive ketone 4-phenylbicyclo<3.3.0>octa-1(5),3,6-triene-2,8-dione has been generated from an insoluble polymeric precursor which was synthetized from chlorosulfonated macromolecular resin and 5-hydroxy-4-phenylbicyclo<3.3.0>octa-3,6-diene-2,8-dione.The liberated diketone can act as a diene but not as a dienophile in the assayed pericyclic reaction.

Full text of DOI:10.1021/jo00198a009

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