Journal of Organic Chemistry p. 4616 - 4618 (1984)
Update date:2022-08-03
Topics:
Gavina, Francisco
Costero, Ana M.
Luis, Santiago V.
The elusive ketone 4-phenylbicyclo<3.3.0>octa-1(5),3,6-triene-2,8-dione has been generated from an insoluble polymeric precursor which was synthetized from chlorosulfonated macromolecular resin and 5-hydroxy-4-phenylbicyclo<3.3.0>octa-3,6-diene-2,8-dione.The liberated diketone can act as a diene but not as a dienophile in the assayed pericyclic reaction.
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