Direct photochemical trifluoromethylation of histidine-containing peptides

DOI: 10.1016/S0040-4039(00)97937-1

Source and publish data:

Tetrahedron Letters p. 5705 - 5708 (1990)

Update date:2022-08-02

Topics:

Authors:

Labroo Labroo

Cohen Cohen

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Article abstract of DOI:10.1016/S0040-4039(00)97937-1

Photochemical trifluoromethylation of the imidazole ring of histidine in the tripeptide Glp-His-Pro-NH₂ (TRH) has been achieved to furnish a mixture of the isomers, 2- and 4(5)-CF₃-Im-TRH, which have been separated by reverse-phase HPLC and characterized.

Full text of DOI:10.1016/S0040-4039(00)97937-1

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