Tetrahedron p. 1629 - 1632 (1984)
Update date:2022-08-03
Topics:
Gurudutt, K. N.
Pasha, M. A.
Ravindranath, B.
Srinivas, P.
Reaction of oxiranes with alkali metals in aprotic solvents yields a variety of products depending on the nature of the metal and the structure of the oxirane.Deoxygenation to olefins is the major reaction in case of lithium.Rearrangement to carbonyl compounds, reduction to alcohols and formation of dimeric products occur when oxiranes are treated with sodium.All the reactions could be rationalised by a mechanism involving an initial single electron transfer leading to the formation of radical-anion intermediate.
View MoreTianjin Hedong Red Cliff Chemical Reagent Factory
Contact:+86-022-84780548
Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
SEA BRGIHT INDUSTRY CO.,LIMITED
Contact:0086 755 8622 3990
Address:Rm 17B3,GuangCaiXinTianDi Bldg,GuiMiao Rd,NanShan District,Shenzhen,China
Shandong Green Bio-Pharmaceutical Co.,Ltd
Contact:+86-530-5408622
Address:High-tech Development Zone, Heze City, Shandong, China
Shijiazhuang Yunxuan Im&Export Co.,Ltd.
Contact:+86-311-83037514
Address:No.6 Hongbin Road
Contact:+49-9398-993127
Address:Untertorstr. 27
Doi:10.1021/jo970669x
(1997)Doi:10.1021/jo062075c
(2007)Doi:10.1021/om0609665
(2007)Doi:10.1039/b612222a
(2007)Doi:10.1021/om970394b
(1997)Doi:10.1016/j.tetlet.2006.11.171
(2007)
