Carbohydrate Research p. 261 - 270 (1984)
Update date:2022-08-05
Topics:
Hanessian, Stephen
Ugolini, Antonio
The stereocontrolled synthesis of a chiral, polyhydroxy 1,7-dioxaspiro<5,5>undecene from D-glucose is described.The bicyclic system with a different pattern of substitution can be found in a number of biologically important natural products such as the avermectins and the milbemycins.
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Doi:10.1021/jacs.8b11658
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