SYNTHESIS OF A CHIRAL 1,7-DIOXASPIROUNDECENE. A MODEL FOR THE SPIROACETAL SUBUNIT OF AVERMECTIN B1a

DOI: 10.1016/0008-6215(84)85284-2

Source and publish data:

Carbohydrate Research p. 261 - 270 (1984)

Update date:2022-08-05

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Authors:

Hanessian, Stephen

Ugolini, Antonio

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Article abstract of DOI:10.1016/0008-6215(84)85284-2

The stereocontrolled synthesis of a chiral, polyhydroxy 1,7-dioxaspiro<5,5>undecene from D-glucose is described.The bicyclic system with a different pattern of substitution can be found in a number of biologically important natural products such as the avermectins and the milbemycins.

Full text of DOI:10.1016/0008-6215(84)85284-2

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