Synthesis of laddersiloxanes by novel stereocontrolled approach

DOI: 10.1016/j.jorganchem.2006.08.068

Source and publish data:

Journal of Organometallic Chemistry p. 307 - 312 (2007)

Update date:2022-07-29

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Authors:

Unno, Masafumi

Matsumoto, Tomoe

Matsumoto, Hideyuki

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Article abstract of DOI:10.1016/j.jorganchem.2006.08.068

Three new pentacyclic laddersiloxanes were prepared by a new method utilizing single stereoisomer of disiloxanediol as a growing unit. Thus, one diastereomer of disiloxanediol, (RS)-[i-PrPhSi(OH)]₂O was isolated and treated with tetrachlorocycl

Full text of DOI:10.1016/j.jorganchem.2006.08.068

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