Chemistry Letters p. 949 - 952 (1984)
Update date:2022-07-29
Topics:
Ichikawa, Junji
Asami, Masatoshi
Mukaiyama, Teruaki
Optically active glycerol derivatives are obtained in up to 84percent e.e. by the selective acylation of the tin(II) alkoxides generated from 2-O-arylsulfonylglycerols and 1,1'-dimethylstannocene or (mehthylcyclopentadienyl)tin(II) chloride by the use of a chiral diamine derived from (S)-proline as a ligand.
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