Carbohydrate Research p. 243 - 250 (1984)
Update date:2022-09-26
Topics:
Nagabhushan, Tattanahalli L.
Turner, William N.
Tsai, Hsinghan
Jaret, Robert S.
Schumacher, Doris
et al.
Sisomicin was converted into 3,2',6'-tri-N-acetylsisomicin by acetylation of its 3'',4''-vicinal-cis and 1,2''-non-vicinal amino-hydroxyl group pair complex of copper(II) or cobalt(II) acetate.The tri-N-blocked derivative was reductively monoalkylated at the 1-position with acetaldehyde and sodium cyanoborohydride and then N-deprotected to give netilmicin.
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(1984)Doi:10.1016/j.bmc.2019.115207
(2019)
