A MODEL FOR OLEFIN HYDRATION: INTRAMOLECULAR NUCLEOPHILIC ADDITION OF PHENOLATE OXYGEN TO THE UNACTIVATED DOUBLE BOND

DOI: 10.1039/P29840001259

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 1259 - 1268 (1984)

Update date:2022-08-04

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Authors:

Evans, Christopher M.

Kirby, Anthony J.

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Article abstract of DOI:10.1039/P29840001259

Two series of phenol-olefins with strained ground states cyclise rapidly to ethers at high pH, where the phenol is fully ionised.The reaction involves intramolecular nucleophilic addition of phenolate oxygen to a monoalkylethylene.A primary carbanion is n

Full text of DOI:10.1039/P29840001259

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