CONVENIENT SYNTHESIS OF (TRIPHENYL)GERMYL AND (TRIPHENYL)STANNYL SUBSTITUTED ALLENES

DOI: 10.1016/0022-328X(84)80703-2

Source and publish data:

Journal of Organometallic Chemistry p. 227 - 234 (1984)

Update date:2022-08-03

Topics:

Authors:

Ruitenberg, K.

Westmijze, H.

Kleijn, H.

Vermeer, P.

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Article abstract of DOI:10.1016/0022-328X(84)80703-2

Allenyl-germanes and -stannanes, Ph3MC(R)=C=CR'R" (M = Ge, Sn) can be obtained, generally in excellent yield, through alkylcopper(I)-induced 1,3-substitution of the propargylic chlorides Ph3MC<*>CCR'R"Cl.In the tin series, however transmetallation is the

Full text of DOI:10.1016/0022-328X(84)80703-2

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