Journal of Organic Chemistry p. 4816 - 4819 (1984)
Update date:2022-07-29
Topics: Cycloadducts Vinylsilane 2,3,3-Trifluoro-1-cyclobutene Dimers of 1,1,2-Trifluoro-1,3-butadiene Tetrafluoroethylene
England, David C.
Weigert, Frank J.
Calabrese, Joseph C.
(Tetrafluorocyclobutyl)silanes prepared by thermal cycloaddition of tetrafluoroethylene (TFE) to vinylsilanes were pyrolyzed at 600 deg C to give mixtures containing dimers of 1,1,2-trifluoro-1,3-butadiene.The monomeric diene 1 was undoubtly an intermediate formed by ring opening of initially formed 2,3,3-trifluoro-1-cyclobutene (9).This cyclobutene has been prepared by fluoride ion catalyzed removal of trimethylfluorosilane from (2,2,3,3-tetrafluorocyclobutyl)trimethylsilane (8) at room temperature.One of the dimers of the diene was saturated and was shown by X-raycrystallography to have the tricyclo<3.3.0.0>octane structure (3) corresponding to a previously reported structure for a perfluorobutadiene dimer.The cyclooctadiene 2 presumed to be the precursor to dimer 3 and Diels-Alder dimers (vinylcyclohexenes) 4 and 7 were characterized by 19F NMR analyses of liquid fractions.
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