Tetrahedron Letters p. 3259 - 3262 (1984)
Update date:2022-08-04
Topics:
Gassman, Paul G.
Gremban, Robert S.
Adjacent hydroxyl, trimethylsiloxyl, and acetoxyl groups have been shown to provide complete control over the regiospecifity of the opening of epoxides by trimethylsilyl cyanide - zinc iodide.Thus, cyclohex-2-en-R-1-ol can be readily converted into (1R,2S,3R)-3-aminocyclohexan-1,2-diol.
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