STEREOCHEMISTRY OF NUCLIOPHILIC ADDITION REACTIONS-13 KINETICALLY CONTROLLED NUCLEOPHILIC ADDITION REACTIONS TO METHYL 4,6-O-BENZYLIDENE-2,3-DIDEOXY-2-NITRO-β-D-ERYTHRO-HEX-2-ENOPYRANOSIDE: AN IMPORTANT ROLE OF A(1,3) STRAIN

DOI: 10.1016/S0040-4020(01)91801-0

Source and publish data:

Tetrahedron p. 1533 - 1540 (1984)

Update date:2022-09-26

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Authors:

Sakakibara, Tohru

Tachimori, Yishifusa

Sudoh, Rokuro

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Article abstract of DOI:10.1016/S0040-4020(01)91801-0

An improved synthesis of methyl 4,6-O-benzylidene-2,3-dideoxy-2-nitro-β-D-erythro-hex-2-enopyranoside and its reactions with various nucleophiles are described; all the nucleophiles were found to approach exclusively or predominantly from the equatorial s

Full text of DOI:10.1016/S0040-4020(01)91801-0

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