Russian Journal of General Chemistry p. 1210 - 1218 (2006)
Update date:2022-08-05
Topics:
Kolotilo
Sinitsa
Rassukanaya
Onys'ko
A procedure for preparing N-sulfonyl-and N- phosphorylbenzimidoylphosphonates by oxidation of the corresponding α-(sulfonylamino)-and α-(phosphorylamino)benzylphosphonates was developed. The σ constants of imidoylphosphonate groups were evaluated by 19F NMR spectroscopy, and specific features of their electronic effects were considered. The reactions of the imidoylphosphonates obtained with O-, S-, P-, and N-nucleophiles were studied. The phosphonate-phosphoramidate rearrangement of α-aminobenzylidene-bisphosphonates was found. Nauka/Interperiodica 2006.
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