PREPARATION OF 2-AMINO-1,6-ANHYDRO-2,3-DIDEOXY-β-D-arabino-HEXOPYRANOSE. 1H- AND 13C-N. M. R. SPECTRA OF DEOXY DERIVATIVES OF 2-AMINO-1,6-ANHYDRO-2-DEOXY-D-GLUCOSE AND 2-AMINO-1,6-ANHYDRO-2-DEOXY-D-MANNOSE

Article abstract of DOI:10.1016/0008-6215(84)85273-8

Partial benzyloxycarbonylation of 1,6-anhydro-D-mannosamine, subsequent mesylation, and treatment with sodium methoxide gave 1,6:3,4-dianhydro-2-benzyloxycarbonylamino-2-deoxy-β-D-altropyranose (9).Oxirane-ring cleavage in 9 with potassium iodide, acetyla