
Tetrahedron p. 2359 - 2364 (1984)
Update date:2022-08-03
Topics:
Nudy, Louis R.
Hutchinson, Howard G.
Schieber, Cherlyann
Longo, Frederick R.
The synthesis and characterizations of 2-bromoporphin, 5-bromoporphin, 5,15-dibromoporphin and 5,10,15-tribromoporphin are described.Yields of the bromoporphins obtained with a variety of brominating agents are reported.Spectral properties were measured and, along with chemical properties, are presented as evidence for a preferred delocalization pathway in porphin.
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