1-Acetoxy-1,3-bis(trimethylsilyl)prop-2-ene. A Synthon for a Propenyl 1,3-Dipole in Diene Synthesis

DOI: 10.1021/jo00199a012

Source and publish data:

Journal of Organic Chemistry p. 4811 - 4816 (1984)

Update date:2022-08-03

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Authors:

Trost, Barry M.

Brandi, Alberto

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Article abstract of DOI:10.1021/jo00199a012

The title reagent undergoes molybdenum-catalyzed alkylation by which it demonstrates its cationic nature.Trimethylsilyl trifluoromethanesulfonate induces direct olefination with aromatic acetals to give (E,E)-1,3-dienes.Fluoride ion serves as a nucleophil

Full text of DOI:10.1021/jo00199a012

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