ZINC-COPPER(I) CHLORIDE OR -SILVER(I) ACETATE PROMOTED ALDOL REACTION OF CHLORODIFLUOROMETHYL KETONES WITH CARBONYL COMPOUNDS. A GENERAL AND EFFECTIVE ROUTE TO α,α-DIFLUORO-β-HYDROXY KETONES

DOI: 10.1016/S0040-4039(00)96894-1

Source and publish data:

Tetrahedron Letters p. 6481 - 6484 (1987)

Update date:2022-08-04

Topics:

Authors:

Kuroboshi, Manabu

Ishihara, Takashi

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Article abstract of DOI:10.1016/S0040-4039(00)96894-1

Chlorodifluoromethyl ketones efficiently underwent the aldol reaction with a variety of aldehydes or ketones in the presence of zinc, a catalytic amount of copper(I) chloride or silver(I) acetate, and molecular sieves to give the corresponding α,α-difluor

Full text of DOI:10.1016/S0040-4039(00)96894-1

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