THE SYNTHESIS OF 3-ACETAMIDO-2,3,5,6-TETRADEOXY-5-FLUORO-D,L-ribo-HEXOFURANOSE BY THE DIRECT FLUORINATION OF METHYL 3-ACETAMIDO-2,3,6-TRIDEOXY-D,L-arabino-HEXOPYRANOSIDE (METHYL N-ACETYL-D,L-ACOSAMINIDE)

DOI: 10.1016/0008-6215(84)85220-9

Source and publish data:

Carbohydrate Research p. 221 - 232 (1984)

Update date:2022-08-02

Topics:

Authors:

Welch, John T.

Svahn, Britt-Marie

Eswarakrishnan, Seetha

Hutchinson, John P.

Zubieta, Jon

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0008-6215(84)85220-9

3-Acetamido-2,3,5,6-tetradeoxy-5-fluoro-D,L-ribo-hexofuranose was synthesized by direct, fluorinative dehydroxylation of methyl 3-acetamido-2,3,6-trideoxy-D,L-arabino-hexopyranoside with sulfur tetrafluoride-hydrogen fluoride.The furanose form and the ribo configuration, indicated by 13C- and 1H-n. m. r. spectroscopy, respectively, were confirmed by a single-crystal, X-ray diffraction study.

Full text of DOI:10.1016/0008-6215(84)85220-9

Products guided by the article

Product name:3-acetamido-2,3,5,6-tetradeoxy-5-fluoro-1-O-(4-nitrobenzoyl)-D,L-ribo-hexofuranose

Cas No:93253-13-5

R&D Labs maybe for 93253-13-5

QINGDAO ON-BILLION INDUSTRAIL CO.,LTD

website:http://www.obn.com.cn

Contact:+86-15005320811 +86-532-80681989

Address:F35 Parkson Mansion No.44-60 Zhongshan Rd.
Nanjing Duly Biotech Co., Ltd

website:http://www.dulynet.com/

Contact:025-84699383 -8003

Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
ShiJiaZhuang Dowell Chemical Co.,Ltd.

website:http://www.dowechem.com

Contact:+86-13463963265

Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
Zhejiang Kaili Industrial Co., Ltd

Contact:+86-571-85241926

Address:lantian business center,No.18 Moganshan Road
Langchem

Contact:+86+21-58956006 15800617331

Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai

Relevant to this article

N-Nosyl as a stereoselectivity-improving and easily removable group in the O-glycosylation of d-allal and d-galactal-derived allyl aziridines. Stereospecific synthesis of 4-amino-2,3-unsaturated-O-glycosides

Doi:10.1016/j.tet.2006.12.069
(2007)
Doi:10.1039/jr9620001148
(1962)
COUMARIN DERIVATIVES FOR MEDICINAL PURPOSES. XVI. SYNTHESIS OF

Doi:10.1248/yakushi1947.83.12_1169
(1963)
Doi:10.1246/bcsj.34.1189
(1961)
Synthesis and biological evaluation of some 4′-C-(hydroxymethyl)- α- and -β-D-arabinofuranosyl pyrimidine and adenine nucleosides

Doi:10.1135/cccc20061063
(2006)
2ZrCl₂ with MAO, MMAO, and AlMe₃/[CPh ₃]⁺[B(C₆F₅)">¹H and¹³C NMR studies of cationic intermediates formed upon activation of "oscillating" catalyst (2-PhInd) ₂ZrCl₂ with MAO, MMAO, and AlMe₃/[CPh ₃]⁺[B(C₆F₅)

Doi:10.1021/om0610694
(2007)

Article Doi