Preparation and X-Ray Structure of a Rhodium(III)-Rhodium(I) Pyrazolate Complex with a Mercury Atom Asymmetrically Bridging the Metal Atoms

DOI: 10.1039/c39840000936

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 936 - 937 (1984)

Update date:2022-08-06

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Authors:

Tiripicchio, Antonio

Lahoz, Fernando J.

Oro, Luis A.

Pinillos, M. Teresa

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Article abstract of DOI:10.1039/c39840000936

Reaction of (1) (pz = pyrazolate) with HgCl2 gives <(Ph3P)(CO)ClRh(μ-HgCl)(μ-pz)2Rh(CO)(PPh3)> (2); the X-ray structure of (2) shows the presence of two rhodium atoms in different oxidation states asymmetrically bridged by a mercury atom, so that a unique Rh^III-Hg <- Rh^I fragment is present.

Full text of DOI:10.1039/c39840000936

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