Journal of the American Chemical Society p. 3078 - 3079 (2007)
Update date:2022-08-05
Topics:
Elliott, Luke D.
Berry, Malcolm
Orr-Ewing, Andrew J.
Booker-Milburn, Kevin I.
UV irradiation of various electron deficient pyrrole derivatives induces a novel methathesis sequence resulting in selective cleavage of the 2,3-pyrrole bond. The overall sequence has been shown to proceed by two discrete wavelength-dependent steps involving sequential [2+2] cyclobutane formation followed by photochemically mediated retro-[2+2] to the products. Copyright
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