Chemistry Letters p. 1093 - 1094 (1997)
Update date:2022-08-04
Topics:
Nakamura, Tomoyuki
Watanabe, Yasumasa
Tezuka, Hiroshi
Busfield, W. Ken
Jenkins, Ian D.
Rizzardo, Ezio
Thang, San H.
Suyama, Shuji
A novel peroxyester, 1,1,2,2-tetramethylpropyl peroxypivalate 1b, has been synthesized and thermolyzed in cumene. The kinetic data show that the decomposition rate constant of 1b is about three times higher than that of tert-butyl peroxypivalate. The radical trapping technique employing 1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindol-2-yloxyl has been used to study the decomposition mechanism of 1b. The results show that the thermolysis of 1b in cumene generates tert-butyl radicals exclusively.
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