Chemistry Letters p. 1093 - 1094 (1997)
Update date:2022-08-04
Topics:
Nakamura, Tomoyuki
Watanabe, Yasumasa
Tezuka, Hiroshi
Busfield, W. Ken
Jenkins, Ian D.
Rizzardo, Ezio
Thang, San H.
Suyama, Shuji
A novel peroxyester, 1,1,2,2-tetramethylpropyl peroxypivalate 1b, has been synthesized and thermolyzed in cumene. The kinetic data show that the decomposition rate constant of 1b is about three times higher than that of tert-butyl peroxypivalate. The radical trapping technique employing 1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindol-2-yloxyl has been used to study the decomposition mechanism of 1b. The results show that the thermolysis of 1b in cumene generates tert-butyl radicals exclusively.
View MoreNanJing Rate Biochemicals CO., LTD
Contact:+86-25-84931986
Address:NO. 1 Hongjing Road,Jiangning Science Park,Nanjing,China
Contact:+86-27-67841589
Address:Add: 999 Gaoxin Road, Donghu New Technology Development Zone, Wuhan City, Hubei, China
Hunan Haili Chemical Industry Co.,Ltd.
Contact:+86-731-85521860
Address:No.251, 2nd Section, Furong Road, Changsha,Hunan,China
Contact:+86-633-8332928
Address:No.1,Huanghai Yilu.Rizhao,Shandong
Changzhou Litong Chemical Co., Ltd.
website:http://www.litonchem.com/
Contact:+86-519-86301238
Address:Laoba Rd, Hutang town Changzhou Jiangsu
Doi:10.1021/ol070276c
(2007)Doi:10.1021/jo01059a080
(1962)Doi:10.1016/j.tetasy.2007.02.006
(2007)Doi:10.1246/bcsj.20100046
(2010)Doi:10.1016/j.poly.2015.07.071
(2015)Doi:10.1021/ol070251d
(2007)
