Total Synthesis of a Mitosene

DOI: 10.1021/jo00200a031

Source and publish data:

Journal of Organic Chemistry p. 5164 - 5174 (1984)

Update date:2022-08-04

Topics:

Authors:

Rebek, Julius

Shaber, Steven H.

Shue, Youe-Kong

Gehret, Jean-Claude

Zimmerman, Stephen

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Article abstract of DOI:10.1021/jo00200a031

The total synthesis of a mitosene (a chemical degradation product of mitomycin C) is described.The synthesis begins with hydroxyproline and uses a Huisgen pyrrole synthesis to form a pyrrolizidine system.The carbocyclic ring is made through Dieckmann cycl

Full text of DOI:10.1021/jo00200a031

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