Journal of the American Chemical Society p. 2358 - 2366 (1986)
Update date:2022-09-26
Topics:
Hendrickson, James B.
Boudreaux, Gerald J.
Palumbo, Paul S.
Mesyltriflone (CF3SO2CH2SO2CH3) is developed as a nuclear synthon reagent capable first of multiple constructions such as alkylations then of Ramberg-Baecklund elimination to a substituted olefin.The alkylations are clean and regiospecific, often amenable to one-pot operation, and in most cases the elimination is smooth.A variety of examples is presented to establish the scope of the method, and the mechanism and stereochemistry are discussed.
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