Stereoselective Synthesis of the B/C/D Ring Systems of Aphidicolane and Stemodane Diterpenes

DOI: 10.1039/c39840000930

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Journal of the Chemical Society. Chemical communications p. 930 - 932 (1984)

Update date:2022-09-26

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Authors:

Iwata, Chuzo

Morie, Toshiya

Maezaki, Naoyoshi

Shimamura, Hisafumi

Tanaka, Tetsuaki

Imanishi, Takeshi

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Article abstract of DOI:10.1039/c39840000930

Diastereoisomeric tricyclo<6.3.1.0^1,6>dodecane derivatives (3) and (4), which correspond to the B/C/D ring systems of aphidicolane and stemodane diterpenes, were selectively prepared from the common spirodienone (5) by means of facile regioselective C-C bond formation mediated by the neighbouring hydroxy group participation.

Full text of DOI:10.1039/c39840000930

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