Journal of the Chemical Society. Chemical communications p. 930 - 932 (1984)
Update date:2022-09-26
Topics:
Iwata, Chuzo
Morie, Toshiya
Maezaki, Naoyoshi
Shimamura, Hisafumi
Tanaka, Tetsuaki
Imanishi, Takeshi
Diastereoisomeric tricyclo<6.3.1.01,6>dodecane derivatives (3) and (4), which correspond to the B/C/D ring systems of aphidicolane and stemodane diterpenes, were selectively prepared from the common spirodienone (5) by means of facile regioselective C-C bond formation mediated by the neighbouring hydroxy group participation.
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