STEREOSELECTIVE SYNTHESIS AND DIELS-ALDER REACTIONS OF BIS-ETHER 1,3 DIENES. A FURTHER TEST FOR COOPERATIVITY DURING CYCLOADDITION REACTIONS.

DOI: 10.1016/0040-4039(84)80108-2

Source and publish data:

Tetrahedron Letters p. 3697 - 3700 (1984)

Update date:2022-08-02

Topics:

Authors:

Gree, Rene

Kessabi, Jilali

Mosset, Paul

Martelli, Jacques

Carrie, Robert

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Article abstract of DOI:10.1016/0040-4039(84)80108-2

A stereoselective synthesis of dienes 1a and 1b, using butadiene-iron tricarbonyl complexes, is described.Higher diastereoselectivity is observed during Diels-Alder reaction of 1a as compared with 1c, affording good evidence for cooperativity in these cycloadditions.

Full text of DOI:10.1016/0040-4039(84)80108-2

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