Wharton Fragmentation of Monosulfonates of Methylhexahydroindandiols

DOI: 10.1021/jo00202a007

Source and publish data:

Journal of Organic Chemistry p. 175 - 179 (1985)

Update date:2022-08-04

Topics:

Authors:

Caine, Drury

McCloskey, Candice J.

Derveer, Donald Van

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Article abstract of DOI:10.1021/jo00202a007

(Z)-5-methylcyclonon-5-en-1-one (5) was obtained by treatment of an 85:15 mixture of 4α- (4a) and 4β-(tosyloxy)-7aβ-hydroxy-3aβ-methyl-3a,4,5,6,7,7a-hexahydroindan (4e) wiyh potassium tert-butoxide in tert-butyl alcohol.The corresponding E isomer (6) was

Full text of DOI:10.1021/jo00202a007

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