A general route for the synthesis of enantiopure indolizidine alkaloids from α-amino acids. Total synthesis of (+)-Monomorine

DOI: 10.1016/S0040-4039(00)60596-8

Source and publish data:

Tetrahedron Letters p. 3985 - 3988 (1993)

Update date:2022-08-03

Topics:

Authors:

Angle, Steven R.

Guy Breitenbucher

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Article abstract of DOI:10.1016/S0040-4039(00)60596-8

The ant trail pheromone (+)-Monomorine was synthesized in 9 steps from N-t-BOC-L-alanine ethyl ester. The key step of the synthesis is the conformationally restricted Claisen rearrangement of lactone 9 to pipecolic ester 11.

Full text of DOI:10.1016/S0040-4039(00)60596-8

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