Metal-assisted, reversible phosphinyl phosphination of the carbon-nitrogen triple bond in a nitrile

DOI: 10.1002/anie.200604622

Source and publish data:

Angewandte Chemie - International Edition p. 2919 - 2922 (2007)

Update date:2022-07-30

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Authors:

Burck, Sebastian

Gudat, Dietrich

Nieger, Martin

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Article abstract of DOI:10.1002/anie.200604622

(Chemical Equation Presented) Split P's: Phosphinyl-substituted N-heterocyclic phosphines react by unprecedented metal-assisted addition of the P-P bond to a nitrile triple bond to give complexes of hybrid bisphosphines. Surprisingly, the addition is reve

Full text of DOI:10.1002/anie.200604622

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