Tandem Conjugate Addition-Aldol Reactions Employing 9-(Phenylseleno)-9-borabicyclononane: A Novel Method for Effecting Formal Aldol Condensations at the α-Carbon of α,β-Unsaturated Ketones

DOI: 10.1021/jo00205a048

Source and publish data:

Journal of Organic Chemistry p. 730 - 732 (1985)

Update date:2022-08-03

Topics:

Authors:

Leonard, William R.

Livinghouse, Tom

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Article abstract of DOI:10.1021/jo00205a048

The title compound has been shown to undergo conjugate addition to a variety of α,β-unsaturated ketones to afford β-seleno boron enolates which are convertable to unsaturated ketols upon treatment with aldehydes and subsequent oxidative elimination.

Full text of DOI:10.1021/jo00205a048

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