Synthesis of all possible stereoisomers of polygodial

DOI: 10.1016/S0040-4039(01)80095-2

Source and publish data:

Tetrahedron Letters p. 1043 - 1046 (1984)

Update date:2022-08-03

Topics:

Authors:

Guillerm, D.

Delarue, M.

Jalali-Naini, M.

Lemaitre, P.

Lallemand, J.-Y.

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Article abstract of DOI:10.1016/S0040-4039(01)80095-2

The three possible isomers of polygodial, epimers at C-9, cis and trans fused, are described.Controlled kinetic and thermodynamic epimerizations allow preparation of all stereoisomers from the same key intermediate.

Full text of DOI:10.1016/S0040-4039(01)80095-2

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