
Tetrahedron Letters p. 1043 - 1046 (1984)
Update date:2022-08-03
Topics:
Guillerm, D.
Delarue, M.
Jalali-Naini, M.
Lemaitre, P.
Lallemand, J.-Y.
The three possible isomers of polygodial, epimers at C-9, cis and trans fused, are described.Controlled kinetic and thermodynamic epimerizations allow preparation of all stereoisomers from the same key intermediate.
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Doi:10.1002/anie.200603972
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