The First Selective Linear Codimerization of Terminal Acetylenes and 1,3-Dienes Catalyzed by Dihydridotetrakis(trialkylphosphine)ruthenium Complexes

DOI: 10.1021/jo00205a005

Source and publish data:

Journal of Organic Chemistry p. 565 - 571 (1985)

Update date:2022-09-26

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Authors:

Mitsudo, Take-aki

Nakagawa, Yoshiteru

Watanabe, Katsuya

Hori, Yoji

Misawa, Hideto

et al. et al.

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Article abstract of DOI:10.1021/jo00205a005

1,3-Butadiene and its derivatives reacted with aliphatic terminal acetylenes in the presence of a catalytic amount of RuH2(P-n-Bu3)4 or RuH2(PEt3)4 in benzene at 60-100 deg C to give linear codimers in high yields with high chemo-, regio-, and stereoselec

Full text of DOI:10.1021/jo00205a005

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