The First Selective Linear Codimerization of Terminal Acetylenes and 1,3-Dienes Catalyzed by Dihydridotetrakis(trialkylphosphine)ruthenium Complexes

DOI: 10.1021/jo00205a005

Source and publish data:

Journal of Organic Chemistry p. 565 - 571 (1985)

Update date:2022-09-26

Topics:

Authors:

Mitsudo, Take-aki

Nakagawa, Yoshiteru

Watanabe, Katsuya

Hori, Yoji

Misawa, Hideto

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00205a005

1,3-Butadiene and its derivatives reacted with aliphatic terminal acetylenes in the presence of a catalytic amount of RuH2(P-n-Bu3)4 or RuH2(PEt3)4 in benzene at 60-100 deg C to give linear codimers in high yields with high chemo-, regio-, and stereoselec

Full text of DOI:10.1021/jo00205a005

Products guided by the article

Product name:Benzene, 1-decen-5-ynyl-, (E)-

Cas No:94426-59-2

R&D Labs maybe for 94426-59-2

Zhejiang Golden-Shell Pharmaceutical Co.,Ltd.

Contact:+86-576-87501888 / 87501988

Address:No.89 Zhongxing Road. Li'ao, Yuhuan, Zhejiang, China
FREEBARQUE DEVELOPMENT GROUP LIMITED

Contact:+86(0)10-5109 5335 or 5109 5345

Address:Room602,Block1-B,LINGDI OFFICE,NO.13 BEIYUAN ROAD
KODI CHEMICAL CO., LTD

Contact:021

Address:Pudong
Shanghai Goyic Pharmaceutical&Chemical Co,. Ltd

Contact:+86-021-60275964

Address:No. 528 ruiqing road
Shanghai Maxchemco Chemical Industry Co., Ltd.

Contact:(86)21-51079223

Address:No.1305-8, B241, the Ecust Park, Huajing Road, Xuhui District, Shanghai

Relevant to this article

Lipophilic N-Hydroxyphthalimide Catalysts for the Aerobic Oxidation of Cumene: Towards Solvent-Free Conditions and Back

Doi:10.1002/chem.201701573
(2017)
Biguanide-functionalized hierarchical porous covalent organic frameworks for efficient catalysis of condensation reactions

Doi:10.1016/j.mcat.2021.111663
(2021)
The synthesis and biological evaluation of a range of novel functionalised benzopyrans as potential potassium channel activators

Doi:10.1016/j.bmcl.2007.11.135
(2008)
Synthesis of (R)-4-Hydroxy-2-benzyloxymethylcyclopent-2-en-1-one from D-Glucose via Palladium(0)-catalysed Rearrangement of a Vinylic Epoxide Intermediate

Doi:10.1039/c39840001040
(1984)
Doi:10.1021/jo01072a018
(1960)
Analogs of nor-B benzomorphane. I. Synthesis of the methano-3,5 tetrahydro-2,3,4,5 1H-benzazepines and derivatives

Doi:10.1002/jhet.5570210422
(1984)

Article Doi