Binding Forces and Catalysis. The Use of Bipyridyl-Metal Chelation to Enhance Reaction Rates

DOI: 10.1021/ja00311a044

Source and publish data:

Journal of the American Chemical Society p. 7487 - 7493 (1985)

Update date:2022-08-05

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Authors:

Rebek, Julius Jr.

Costello, Timothy

Wattley, Ruth

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Article abstract of DOI:10.1021/ja00311a044

The application of a binding force (the chelation of a metal by a 2,2'-bipyridyl) to enhance reaction rates is examined with three systems.Metals are shown to increase the rate of cyclization of certain 3,3'-disubstituted, 2,2'-bipyridyl derivatives.Simil

Full text of DOI:10.1021/ja00311a044

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