A New Synthesis of Bicycloocta-2,4-diene and Its Cycloaddition Reactions with Dienophiles.

DOI: 10.1021/jo00204a022

Source and publish data:

Journal of Organic Chemistry p. 531 - 534 (1985)

Update date:2022-08-03

Topics:

Authors:

Yin, Tyze-Kuan

Lee, Jon Gun

Borden, Weston Thatcher

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Article abstract of DOI:10.1021/jo00204a022

Bicyclo<4.1.1>octa-2,4-diene (4) has been synthesized by a new, nine-step route, starting from 2-<(trimethylsilyl)oxy>-1,3-butadiene and acrolein.Diene (4) proved almost as unreactive toward Diels-Alder cycloadditions as the previously studied 7,7-dimethy

Full text of DOI:10.1021/jo00204a022

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