Preparation and use of enantioenriched Allenylsilanes for the stereoselective synthesis of homopropargylic ethers

DOI: 10.1021/ol070936d

Source and publish data:

Organic Letters p. 2689 - 2692 (2007)

Update date:2022-07-30

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Authors:

Brawn, Ryan A.

Panek, James S.

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Article abstract of DOI:10.1021/ol070936d

Equation Presented A convenient procedure for the synthesis of highly enantioenriched allenylsilanes by Johnson orthoester Claisen rearrangement of 1-silyl propargylic alcohols is described. Allenylsilanes are then used as carbon nucleophiles in three-com

Full text of DOI:10.1021/ol070936d

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