ORGANOCERIUM REAGENTS. NUCLEOPHILIC ADDITION TO EASILY ENOLIZABLE KETONES

DOI: 10.1016/S0040-4039(01)81404-0

Source and publish data:

Tetrahedron Letters p. 4233 - 4236 (1984)

Update date:2022-08-02

Topics:

Authors:

Imamato, Tsuneo

Sugiura, Yasushi

Takiyama, Nobuyuki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)81404-0

Organocerium reagens, prepared from organolithiums and anhydrous cerium (III) chloride, react cleanly with easily enolizable ketones to afford the addition products in good to excellent yields.

Full text of DOI:10.1016/S0040-4039(01)81404-0

Products guided by the article

Product name:(8S,9S,10R,13R,14S,17R)-17-((R)-1,5-Dimethyl-hexyl)-10,13-dimethyl-3-phenylethynyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-ol

Cas No:94632-37-8

R&D Labs maybe for 94632-37-8

Huangshi Meifeng Chemical Co.,ltd.

Contact:+86-714-6516706

Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China
Shaanxi HuaTai Bio-fine chemical company Ltd

Contact:86-029-87862197

Address:No. 5, 3rd Floor, 29 Yanta North Road, Beilin Dist.
Changsha Yonta Industry Co., Ltd.

Contact:+ 86-731-8535 2228

Address:Rm.1717, North Bldg., No.368, East 2nd Ring Road(2nd Section)
Henan zhongda Biological Engineering Co., Ltd

Contact:86-28-18109029985

Address:shenzhou road,xuedian industrial estate,zhengzhou city,henan province CHN
NINGBO YINLIANG FOREIGN TRADE CO., LTD.

Contact:+86-574-87834016 / 87898057

Address:23F NO.666JINYU ROAD,YINGZHOU DISTRICT,NINGBO.CHINA

Relevant to this article

Stereoselective synthesis of vinylic chalcogenides through vinylic substitution by lithium organylchalcogenolates

Doi:10.1016/j.tetlet.2007.05.074
(2007)
Diastereoselective synthesis of arylglycine derivatives by cationic palladium(ll)-catalyzed addition of arylboronic acids to N-tert-butanesulfinyl imino esters

Doi:10.1021/ol0711220
(2007)
Design, synthesis, and biological activity of folate receptor-targeted prodrugs of thiolate histone deacetylase inhibitors

Doi:10.1016/j.bmcl.2007.05.040
(2007)
SYNTHESIS OF dl-SEPTICINE

Doi:10.1246/cl.1980.383
(1980)
Modified Preparation Method of Trifluoromethylated Propargylic Alcohols and Its Application to Chiral 2,6-Dideoxy-6,6,6-trifluorosugars

Doi:10.1021/jo00124a013
(1995)
Domino Michael-seleno Pummerer type reaction (additive seleno Pummerer reaction)

Doi:10.1039/b004912n
(2000)

Article Doi