Regiochemical Control of the Ring-Opening of 1,2-Epoxides by Means of Chelating Processes. 2. Synthesis and Reactions of the cis- and trans-Oxides of 4-cyclohexene, 3-Cyclohexenemethanol, and Methyl 3-Cyclohexenecarboxylate

DOI: 10.1021/jo00031a018

Source and publish data:

Journal of Organic Chemistry p. 1405 - 1412 (1992)

Update date:2022-08-04

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Authors:

Chini, Marco

Crotti, Paolo

Flippin, Lee A.

Macchia, Franco

Pineschi, Mauro

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Article abstract of DOI:10.1021/jo00031a018

The synthesis of the diastereoisomeric epoxides cis-1b-d and trans-2b-d and the products of their ring-opening by various nucleophiles are described.The results of the ring-openings of the trans-epoxides 2b-d can be rationalized by combining stereoelectro

Full text of DOI:10.1021/jo00031a018

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