Chemistry of Natural Compounds p. 354 - 357 (1984)
Update date:2022-08-05
Topics:
Balezina, G. G.
Ishmuratov, G. Yu.
Odinokov, V. N.
Selimov, F. A.
Dzhemilev, U. M.
Tolstikov, G. A.
A method has been developed for the stereospecific synthesis of (Z)-dodeca-9,11-dienyl acetate, a component, together with the corresponding (E) isomer, of the sex pheromone of the red cotton bollworm moth, that is based on the coupling of vinylacetylene with either 8-hydroxyoctanal or 8-bromoctan-1-ol to form a C12 enynic compound in which the acetylenic bond is then reduced stereospecifically with 9-borabicyclo<3.3.1>nonane.
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