An η2 Transition State for thw Insertion of Fragments into the Phosphorus-Carbon Bonds of Phosphiranepentacarbonyltungsten Complexes. Crystal and Molecular Structures of (2R,3S,4R)- and (2R,3S,4S)-,dppe=1,2-bis(diphenylphosphanyl)ethane

DOI: 10.1039/c39890001389

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1389 - 1390 (1989)

Update date:2022-07-29

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Authors:

Carmichael, Duncan

Hitchcock, Peter B.

Nixon, John F.

Mathey, Francois

Ricard, Louis

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Article abstract of DOI:10.1039/c39890001389

Evidence for a transition state involving η² co-ordination of a P-C bond to is obtained from an analysis of the insertion of fragments into (E)- and (Z)- complexes.

Full text of DOI:10.1039/c39890001389

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