TOTAL SYNTHESIS OF (+/-)-KARATAVIC ACID: STRUCTURE CONFIRMATION OF THE FIRST SECO-DRIMANE TYPE SESQUITERPENOID

DOI: 10.1016/S0040-4039(00)99905-2

Source and publish data:

Tetrahedron Letters p. 437 - 440 (1984)

Update date:2022-08-04

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Authors:

Nishizawa, Mugio

Takenaka, Hideyuki

Hayashi, Yuji

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Article abstract of DOI:10.1016/S0040-4039(00)99905-2

One of the postulated structures of karavatic acid is confirmed via the total synthesis by means of the mercury(II) triflate/amine complex-induced olefin cyclization and subsequent short step transformations.Stereochemistry of this new class of natural pr

Full text of DOI:10.1016/S0040-4039(00)99905-2

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