Bulletin of the Chemical Society of Japan p. 1357 - 1367 (2007)
Update date:2022-08-04
Topics:
Nishioka, Takanori
Mitsui, Shigeru
Kinoshita, Isamu
Koshiyama, Tamami
Kato, Masako
A dinucleating ligand consisting of thiopyridyl groups appended to a p-xylene backbone reacts with copper(I) halides to afford dinuclear copper complexes with terminal halogeno ligands, which are in equilibrium with bridging halogeno dicopper complexes formed by rearrangement and loss one of the terminal halogeno ligands. The identity of the products was confirmed by using 1HNMR spectroscopy, electrospray ionization mass spectrometry, and X-ray structure analyses.
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