Tetrahedron Letters p. 5452 - 5455 (2009)
Update date:2022-08-03
Topics:
Horne, Daniel B.
Bartberger, Michael D.
Kaller, Matthew R.
Monenschein, Holger
Zhong, Wenge
Hitchcock, Stephen A.
We report the efficient synthesis of difluoroalkyl aryl ethers from the rearrangement of heteroaryl ketones and aldehydes, mediated by xenon difluoride and HF/pyridine in methylene chloride at room temperature. Computational analysis of difluoroalkylether
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